Crystal structure of di-ethano-lbis(thio-cyanato)-bis(urotropine)cobalt(II) and tetra-ethano-lbis(thio-cyanato)-cobalt(II)-urotropine (1/2).

ABSTRACT: The reaction of one equivalent Co(NCS)₂ with four equivalents of urotropine (hexa-methyl-ene-tetra-mine) in ethanol leads to the formation of two compounds, namely, bis-(ethanol-κO)bis-(thio-cyanato-κN)bis-(urotropine-κN)cobalt(II), [Co(NCS)₂(C₆H₁₂N₄)₂(C₂H₆O)₂] (1), and tetra-kis-(ethanol-κO)bis-(thio-cyanato-κN)cobalt(II)-urotropine (1/2), [Co(NCS)₂(C₂H₆O)₄]·2C₆H₁₂N₄ (2). In 1, the Co cations are located on centers of inversion and are sixfold coordinated by two terminal N-bonded thio-cyanate anions, two ethanol and two urotropine ligands whereas in 2 th

SUBMITTER: Krebs C 

PROVIDER: S-EPMC8739191 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature