Crystal structures of two novel iron isocyanides from the reaction of 2,6-di-methyl-phenyl isocyanide, CNXyl, with bis-(anthracene)ferrate(-1).

ABSTRACT: The reaction of the [K(18-crown-6)(thf)₂]¹⁺ (thf is tetra-hydro-furan) salt of bis-(anthracene)ferrate(-1), or [Fe(C₁₄H₁₀)₂]^-, with 2,6-di-methyl-phenyl isocyan-ide (CNX-yl) in thf resulted in the formation of two new iron isocyanide complexes, namely, [(1,2,3,4-η)-anthracene]tris-(2,6-di-methyl-phenyl isocyanide)iron, [Fe(C₁₄H₁₀)(C₉H₉N)₃] or [Fe(1,2,3,4-η-C₁₄H₁₀)(CNX-yl)₃], and {5,6-bis-(2,6-di-methyl-anilino)-3-(2,6-di-methyl-phen-yl)-1,2,7-tris-[(2,6-di-methyl-phen-yl)imino]-3-azoniahept-3-ene-1,4,7-triido}tris-(2,6-di-methyl-phenyl isocyanide)iron tetra-hydro-furan disolvate, [Fe(C₅₄H₅₆N₆)(C₉

SUBMITTER: Brennessel WW 

PROVIDER: S-EPMC8739210 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature