N═N Bond Cleavage by Tantalum Hydride Complexes: Mechanistic Insights and Reactivity.

ABSTRACT: The reaction of [TaCp^RX₄] (Cp^R = η⁵-C₅Me₅, η⁵-C₅H₄SiMe₃, η⁵-C₅HMe₄; X = Cl, Br) with SiH₃Ph resulted in the formation of the dinuclear hydride tantalum(IV) compounds [(TaCp^RX₂)₂(μ-H)₂], structurally identified by single-crystal X-ray analyses. These species react with azobenzene to give the mononuclear imide complex [TaCp^RX₂(NPh)] along with the release of molecular hydrogen. Analogous reactions between the [{Ta(η⁵-C₅Me₅)X₂}₂(μ-H)₂] derivatives and the cyclic diazo reagent benzo[c]cinnoline afford the

SUBMITTER: Alvarez-Ruiz E 

PROVIDER: S-EPMC8753601 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature