Assembly of Polyiodide Networks with Cu(II) Complexes of Pyridinol-Based Tetraaza Macrocycles.

ABSTRACT: Polyiodide networks are currently of great practical interest for the preparation of new electronic materials. The participation of metals in the formation of these networks is believed to improve their mechanical performance and thermal stability. Here we report the results on the construction of polyiodide networks obtained using Cu(II) complexes of a series of pyridinol-based tetraazacyclophanes as countercations. The assembly of these crystalline polyiodides takes place from aqueous solutions on the basis of similar structural elements, the [CuL]²⁺ and [Cu(H_-1L)]⁺ (L = L2, L2-Me, L2-Me₃) complex cations, so that the peculiarities induced by the increase of N-methylation of ligands, the structural variable of ligand

SUBMITTER: Martinez-Camarena A 

PROVIDER: S-EPMC8753606 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature