Magneto-structural Correlations in Ni²⁺-Halide···Halide-Ni²⁺ Chains.

ABSTRACT: We present the magnetic properties of a new family of S = 1 molecule-based magnets, NiF₂(3,5-lut)₄·2H₂O and NiX₂(3,5-lut)₄, where X = HF₂, Cl, Br, or I (lut = lutidine C₇H₉N). Upon creation of isolated Ni-X···X-Ni and Ni-F-H-F···F-H-F-Ni chains separated by bulky and nonbridging lutidine ligands, the effect that halogen substitution has on the magnetic properties of transition-metal-ion complexes can be investigated directly and in isolation from competing processes such as Jahn-Teller distortions. We find that substitution of the larger halide ions turns on increasingly strong antiferromagnetic interactions between adjacent Ni²⁺ ions via a novel through-space two-halide exchange. In t

SUBMITTER: Blackmore WJA 

PROVIDER: S-EPMC8753652 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature