Adsorption-Desorption Behavior of Arsenate Using Single and Binary Iron-Modified Biochars: Thermodynamics and Redox Transformation.

ABSTRACT: Arsenic (As) is a dangerous contaminant in drinking water which displays cogent health risks to humans. Effective clean-up approaches must be developed. However, the knowledge of adsorption-desorption behavior of As on modified biochars is limited. In this study, the adsorption-desorption behavior of arsenate (As^V) by single iron (Fe) and binary zirconium-iron (Zr-Fe)-modified biosolid biochars (BSBC) was investigated. For this purpose, BSBC was modified using Fe-chips (FeBSBC), Fe-salt (FeCl₃BSBC), and Zr-Fe-salt (Zr-FeCl₃BSBC) to determine the adsorption-desorption behavior of As^V using a range of techniques. X-ray photoelectron spectroscopy results revealed the partial reduction of pentavalent As^V to the more toxic trivalent As

SUBMITTER: Rahman MA 

PROVIDER: S-EPMC8756808 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature