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Effect of Polymer Molecular Mass and Structure on the Mechanical Properties of Polymer-Glass Hybrids.

ABSTRACT: Organic-inorganic hybrid materials are a promising class of materials for tissue engineering and other biomedical applications. In this systematic study, the effect of the polymer molecular mass (MM) with a linear architecture on hybrid mechanical properties is reported. Well-defined linear poly(methyl methacrylate-co-(3-(trimethoxysilyl)propyl methacrylate)) polymers with a range of MMs of 9 to 90 kDa and one 90 kDa star-shaped polymer were synthesized and then used to form glass-polymer hybrids. It was demonstrated that increasing linear polymer MM decreases the resultant hybrid mechanical strength. Furthermore, a star-polymer hybrid was synthesized as a comparison and demonstrated significantly different mechanical properties relative to its linear-polymer counterpart.

SUBMITTER: Lee YL

PROVIDER: S-EPMC8757365 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature

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Effect of Polymer Molecular Mass and Structure on the Mechanical Properties of Polymer-Glass Hybrids.

Lee Yu Lin YL Lester Daniel W DW Jones Julian R JR Georgiou Theoni K TK

ACS omega 20211222 1

Organic-inorganic hybrid materials are a promising class of materials for tissue engineering and other biomedical applications. In this systematic study, the effect of the polymer molecular mass (MM) with a linear architecture on hybrid mechanical properties is reported. Well-defined linear poly(methyl methacrylate-<i>co</i>-(3-(trimethoxysilyl)propyl methacrylate)) polymers with a range of MMs of 9 to 90 kDa and one 90 kDa star-shaped polymer were synthesized and then used to form glass-polymer ...[more]

PMID: 35036745

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