A comprehensive kinetic model for phenol oxidation in seven advanced oxidation processes and considering the effects of halides and carbonate.

ABSTRACT: As one of the most powerful approaches to mechanistically understanding complex chemical reactions and performing simulations or predictions, kinetic modeling has been widely used to investigate advanced oxidation processes (AOPs). However, most of the available models are built based on limited systems or reaction mechanisms so they cannot be readily extended to other systems or reaction conditions. To overcome such limitations, this study developed a comprehensive model on phenol oxidation using over 540 reactions, covering the most common reaction mechanisms in nine AOPs-four peroxymonosulfate (PMS), four peroxydisulfate (PDS), and one H₂O₂ systems-and considering product formation and the effects of co-existing anions (chloride, bromide, and carbonate). Existing m

SUBMITTER: Huang K 

PROVIDER: S-EPMC8766555 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature