Mid-infrared-perturbed molecular vibrational signatures in plasmonic nanocavities.

ABSTRACT: Recent developments in surface-enhanced Raman scattering (SERS) enable observation of single-bond vibrations in real time at room temperature. By contrast, mid-infrared (MIR) vibrational spectroscopy is limited to inefficient slow detection. Here we develop a new method for MIR sensing using SERS. This method utilizes nanoparticle-on-foil (NPoF) nanocavities supporting both visible and MIR plasmonic hotspots in the same nanogap formed by a monolayer of molecules. Molecular SERS signals from individual NPoF nanocavities are modulated in the presence of MIR photons. The strength of this modulation depends on the MIR wavelength, and is maximized at the 6-12 μm absorption bands of SiO₂ or polystyrene placed under the foil. Using a single-photon lock-in detection scheme we time-resol

SUBMITTER: Chikkaraddy R 

PROVIDER: S-EPMC8766566 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature