Heavy atom oriented orbital angular momentum manipulation in metal-free organic phosphors.

ABSTRACT: Metal-free purely organic phosphors (POPs) are emerging materials for display technologies, solid-state lighting, and chemical sensors. However, due to limitations in contemporary design strategies, the intrinsic spin-orbit coupling (SOC) efficiency of POPs remains low and their emission lifetime is pinned in the millisecond regime. Here, we present a design concept for POPs where the two main factors that control SOC-the heavy atom effect and orbital angular momentum-are tightly coupled to maximize SOC. This strategy is bolstered by novel natural-transition-orbital-based computational methods to visualize and quantify angular momentum descriptors for molecular design. To demonstrate the effectiveness of this strategy, prototype POPs were created having efficient room-temperature phosphore

SUBMITTER: Shao W 

PROVIDER: S-EPMC8768842 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature