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ABSTRACT:
SUBMITTER: Otsubo K
PROVIDER: S-EPMC8790730 | biostudies-literature | 2022 Jan
REPOSITORIES: biostudies-literature
Otsubo Kazuya K Nagayama Shuya S Kawaguchi Shogo S Sugimoto Kunihisa K Kitagawa Hiroshi H
JACS Au 20220103 1
Metal-organic frameworks (MOFs), made from various metal nodes and organic linkers, provide diverse research platforms for proton conduction. Here, we report on the superprotonic conduction of a Pt dimer based MOF, [Pt<sub>2</sub>(MPC)<sub>4</sub>Cl<sub>2</sub>Co(DMA)(HDMA)·guest] (H<sub>2</sub>MPC, 6-mercaptopyridine-3-carboxylic acid; DMA, dimethylamine). In this framework, a protic dimethylammonium cation (HDMA<sup>+</sup>) is trapped inside a pore through hydrogen bonding with an MPC ligand. ...[more]