Multiobjective Evaluation of Amine-Based Absorbents for SO₂ Capture Process Using the pK _a Mathematical Model.

ABSTRACT: The screening of high-efficiency and low-energy consumption absorbents is critical for capturing SO₂. In this study, absorbents with better performance are screened based on mechanism, model, calculation, verification, and analysis methods. The acidity coefficient (pK _a) values of ethylenediamine (EDA), piperazine (PZ), 1-(2-hydroxyethyl)piperazine (HEP), 1,4-bis(2-hydroxyethyl)piperazine (DIHEP), and 1-(2-hydroxyethyl)-4-(2-hydroxypropyl)piperazine (HEHPP) are calculated by quantum chemical methods. A mathematical model of the SO₂ cyclic absorption capacity per amine (α_c) in the amine-based SO₂ capture process is built based on the electroneutrality of the solution. Another model of desorption reaction heat (Q _des</

SUBMITTER: Wang D 

PROVIDER: S-EPMC8792931 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature