Electrochemical Signatures of Interface-Dominated Behavior in the Testing of Calcium Foil Anodes.

ABSTRACT: Fundamental research and practical assembly of rechargeable calcium (Ca) batteries will benefit from an ability to use Ca foil anodes. Given that Ca electrochemistry is considered a surface-film-controlled process, understanding the interface's role is paramount. This study examines electrochemical signatures of several Ca interfaces in a benchmark electrolyte, Ca(BH4)2/tetrahydrofuran (THF). Preparation methodologies of Ca foils are presented, along with Ca plating/stripping through either pre-existing, native calcium hydride (CaH2), or pre-formed calcium fluoride (CaF2) interfaces. In contrast to earlier work examining Ca foil in other electrolytes, Ca foils are accessible for reversible electrochemistry in Ca(BH4)2/THF. However, the first cyclic voltammetry (CV) cycle reflects persisten

SUBMITTER: Melemed AM 

PROVIDER: S-EPMC8793006 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature