Thermodynamics and Catalytic Properties of Two Novel Energetic Complexes Based on 3-Amino-1,2,4-triazole-5-carboxylic Acid.

ABSTRACT: For energetic materials (EMs), the key point of the present research is to improve the energetic property and reduce sensitivity. In this work, two new energetic complexes, Mn(atzc)₂(H₂O)₂·2H₂O (1) and Zn(atzc)₂(H₂O) (2) (Hatzc = 3-amino-1,2,4-triazole-5-carboxylic acid), were synthesized by solvent evaporation and diffusion methods, respectively. The structural analyses illustrate that 1 and 2 exhibit zero-dimensional structural units, which are linked by hydrogen-bonding interactions to give three-dimensional supramolecular architectures. For complexes 1 and 2, the detonation velocities (D) are 10.4 and 10.2 km·s^-1 and detonation pressures (P) are 48.7 and 48.6 GP

SUBMITTER: Song H 

PROVIDER: S-EPMC8793045 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature