Luminescent cis-Bis(bipyridyl)ruthenium(II) Complexes with 1,2-Azolylamidino Ligands: Photophysical, Electrochemical Studies, and Photocatalytic Oxidation of Thioethers.

ABSTRACT: New 1,2-azolylamidino complexes cis-[Ru(bipy)₂(NH═C(R)az*-κ²N,N)](OTf)₂ (R = Me, Ph; az* = pz, indz, dmpz) are synthesized via chloride abstraction after a subsequent base-catalyzed coupling of a nitrile with the previously coordinated 1,2-azole. The synthetic procedure allows the easy obtainment of complexes having different electronic and steric 1,2-azoylamidino ligands. All of the compounds have been characterized by ¹H, ¹³C, and ¹⁵N NMR and IR spectroscopy and by monocrystal X-ray diffraction. Photophysical studies support their phosphorescence, whereas their electrochemistry reveals reversible Ru^II/Ru^III oxidations between +1.13 and +1.25 V (vs SCE). The complexes have been suc

SUBMITTER: Cuellar E 

PROVIDER: S-EPMC8812113 | biostudies-literature | 2021 May

REPOSITORIES: biostudies-literature