The Role of Cation Acidity on the Competition between Hydrogen Evolution and CO₂ Reduction on Gold Electrodes.

ABSTRACT: CO₂ electroreduction (CO₂RR) is a sustainable alternative for producing fuels and chemicals. Metal cations in the electrolyte have a strong impact on the reaction, but mainly alkali species have been studied in detail. In this work, we elucidate how multivalent cations (Li⁺, Cs⁺, Be²⁺, Mg²⁺, Ca²⁺, Ba²⁺, Al³⁺, Nd³⁺, and Ce³⁺) affect CO₂RR and the competing hydrogen evolution by studying these reactions on polycrystalline gold at pH = 3. We observe that cations have no effect on proton reduction at low overpotentials, but at alkaline surface pH acidic cations undergo hydrolysis, generating a second proton reduction regime. The activity and onset for the water re

SUBMITTER: Monteiro MCO 

PROVIDER: S-EPMC8815072 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature