Dynamic structural evolution of iron catalysts involving competitive oxidation and carburization during CO₂ hydrogenation.

ABSTRACT: Identifying the dynamic structure of heterogeneous catalysts is crucial for the rational design of new ones. In this contribution, the structural evolution of Fe(0) catalysts during CO₂ hydrogenation to hydrocarbons has been investigated by using several (quasi) in situ techniques. Upon initial reduction, Fe species are carburized to Fe₃C and then to Fe₅C₂. The by-product of CO₂ hydrogenation, H₂O, oxidizes the iron carbide to Fe₃O₄. The formation of Fe₃O₄@(Fe₅C₂+Fe₃O₄) core-shell structure was observed at steady state, and the surface composition depends on the balance of oxidation and carburization, where water plays a key role in the o

SUBMITTER: Zhu J 

PROVIDER: S-EPMC8816344 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature