Regulation of Surface Structure of [Au₉Ag₁₂(SAdm)₄(Dppm)₆Cl₆](SbF₆)₃ Nanocluster via Alloying.

ABSTRACT: Tailoring of specific sites on the nanocluster surface can tailor the properties of nanoclusters at the atomic level, for the in-depth understanding of structure and property relationship. In this work, we explore the regulation of surface structure of [Au₉Ag₁₂(SAdm)₄(Dppm)₆Cl₆](SbF₆)₃ nanocluster via alloying. We successfully obtained the well-determined tri-metal [Au₉Ag₈@Cu₄(SAdm)₄(Dppm)₆Cl₆](SbF₆)₃ by the reaction of [Au₉Ag₁₂(SAdm)₄(Dppm)₆Cl₆](SbF₆)₃ with the Cu^I(SAdm) complex precursor. X-ray crystallography identifies that the Cu

SUBMITTER: Deng H 

PROVIDER: S-EPMC8819595 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature