A metal-supported single-atom catalytic site enables carbon dioxide hydrogenation.

ABSTRACT: Nitrogen-doped graphene-supported single atoms convert CO₂ to CO, but fail to provide further hydrogenation to methane - a finding attributable to the weak adsorption of CO intermediates. To regulate the adsorption energy, here we investigate the metal-supported single atoms to enable CO₂ hydrogenation. We find a copper-supported iron-single-atom catalyst producing a high-rate methane. Density functional theory calculations and in-situ Raman spectroscopy show that the iron atoms attract surrounding intermediates and carry out hydrogenation to generate methane. The catalyst is realized by assembling iron phthalocyanine on the copper surface, followed by in-situ formation of single iron atoms during electrocatalysis, identified using operando X-ray absorption spectrosco

SUBMITTER: Hung SF 

PROVIDER: S-EPMC8831533 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature