Structural Diversity of Silver Fluorinated β-Diketonates: Effect of the Terminal Substituent and Solvent.

ABSTRACT: In order to demonstrate the role of the fluorination and some solvents in the structural organization of the Ag(I) coordination polymers with β-diketonate ligands (R1C(O)CαHC(O)R2)- we synthesized a series of the compounds containing tfac- (R1 = CH3, R2 = CF3) and pfpac- (R1 = CH3, R2 = C2F5) anions. Solvent-free [Ag(L)]∞ (L = tfac 1, pfpac 2) compounds and the corresponding acetonitrile and toluene adducts have been characterized by elemental analysis and/or NMR, IR and single-crystal XRD. This series includes five new coordination polymers. Compound 1 is a 3D coordination framework based on Ag-Ochelate/bridge, Ag-Cα bonds, and argentophilic interactions. An increase in the fluorinated group leads to a chain coordination polymer 2 of an unusual structural organization. These chains can be

SUBMITTER: Vikulova ES 

PROVIDER: S-EPMC8839988 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature