In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol.
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ABSTRACT: Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 °C under 20 bar of H2 pressure.
SUBMITTER: Bruna L
PROVIDER: S-EPMC8840484 | biostudies-literature | 2022 Jan
REPOSITORIES: biostudies-literature
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