Efficient Photoinduced Electron Transfer from Pyrene-o-Carborane Heterojunction to Selenoviologen for Enhanced Photocatalytic Hydrogen Evolution and Reduction of Alkynes.

ABSTRACT: A series of pyrene or pyrene-o-carborane-appendant selenoviologens (Py-SeV²⁺ , Py-Cb-SeV²⁺ ) for enhanced photocatalytic hydrogen evolution reaction (HER) and reduction of alkynes is reported. The efficient photoinduced electron transfer (PET) from electron-rich pyrene-o-carborane heterojunction (Py-Cb) with intramolecular charge transfer (ICT) characteristic to electron-deficient selenoviologen (SeV²⁺ ) (k_ET = 1.2 × 10¹⁰ s^-1 ) endows the accelerating the generation of selenoviologen radical cation (SeV^+• ) compared with Py-SeV²⁺ and other derivatives. The electrochromic/electrofluorochromic devices' (ECD and EFCD) measurements and supramolecular assembly/disassembly processes of SeV²⁺ and cu

SUBMITTER: Yang X 

PROVIDER: S-EPMC8844576 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature