Oxidative coupling of methane-comparisons of MnTiO₃-Na₂WO₄ and MnO_x-TiO₂-Na₂WO₄ catalysts on different silica supports.

ABSTRACT: The oxidative coupling of methane (OCM) converts CH₄ to value-added chemicals (C₂₊), such as olefins and paraffin. For a series of MnTiO₃-Na₂WO₄ (MnTiO₃-NW) and MnO_x-TiO₂-Na₂WO₄ (Mn-Ti-NW), the effect of loading of MnTiO₃ or MnO_x-TiO₂, respectively, on two different supports (sol-gel SiO₂ (SG) and commercial fumed SiO₂ (CS)) was examined. The catalyst with the highest C₂₊ yield (21.6% with 60.8% C₂₊ selectivity and 35.6% CH₄ conversion) was 10 wt% MnTiO₃-NW/SG with an olefins/paraffin ratio of 2.2. The catalyst surfaces with low oxygen-binding energies were associated with high CH

SUBMITTER: Tiyatha W 

PROVIDER: S-EPMC8850452 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature