Exploring the Effects of Organic Matter Characteristics on Fe(II) Oxidation Kinetics in Coastal Seawater.

ABSTRACT: The iron(II) oxidation kinetic process was studied at 25 stations in coastal seawater of the Macaronesia region (9 around Cape Verde, 11 around the Canary Islands, and 5 around Madeira). In a physicochemical context, experiments were carried out to study the pseudo-first-order oxidation rate constant (k', min^-1) over a range of pH (7.8, 7.9, 8.0, and 8.1) and temperature (10, 15, 20, and 25 °C). Deviations from the calculated k_cal^' at the same T, pH, and S were observed for most of the stations. The measured t_1/2 (ln 2/k', min) values at the 25 stations ranged from 1.82 to 3.47 min (mean 1.93 ± 0.76 min) and for all but two stations were lower than the calculated t_1/2 of 3.21 ± 0.2 min. In a biogeoche

SUBMITTER: Santana-Casiano JM 

PROVIDER: S-EPMC8851691 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature