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Electrochemical evaluation of porous CaFe2O4 anode material prepared via solution combustion synthesis at increasing fuel-to-oxidizer ratios and calcination temperatures.


ABSTRACT: The drawbacks of common anodes in lithium-ion batteries (LIBs) and hybrid supercapacitors (HSCs), such as the high voltage plateau of Li4Ti5O12 (1.55 V vs. Li/Li+) and the moderate capacity of graphite (372 mAh-g-1), have established a need for better materials. Conversion materials, and in particular iron oxide and CaFe2O4 (CFO), have amassed recent attention as potential anode replacements. In this study, we evaluate the material and electrochemical effects of the solution combustion synthesis (SCS) of porous CFO across novel fuel-to-oxidizer ratios and calcination temperatures. We demonstrate that nearly doubling the amount of fuel used during synthesis increases capacities between 120 and 150% at high current

SUBMITTER: Strimaitis J 

PROVIDER: S-EPMC8866530 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature