End-Terminated Poly(urethane-urea) Hybrid Approach toward Nanoporous/Microfilament Morphology.

ABSTRACT: In the present work, the effect of heteroatomic hydrogen bonding on the properties of -OH/-NH-terminated soft-segment-free polymers, viz, polyurethane (P-UT), polyurea (P-UR), and their hybrid (P-UT-UR), is explored. P-UT was synthesized from phloroglucinol and P-UR was synthesized from 1,3,5-triazine-2,4,6-triamine by employing hexamethylene diisocyanate as a counterpart. P-UT exhibited a spherulitic structure with varying sizes, whereas P-UR displayed a fibrillar structure characteristic as that of crystalline hard segments. The P-UT-UR hybrid exhibited a fine nanospherulitic structure with a high order of interconnectivity. Negative surface skewness values of -0.47 and -0.18 were measured (by AFM) for P-UT and P-UT-UR, respectively, which revealed that the surface is not smooth a

SUBMITTER: Veetil RE 

PROVIDER: S-EPMC8867484 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature