An NHC-Mediated Metal-Free Approach towards an NHC-Coordinated Endocyclic Disilene.

ABSTRACT: A convenient metal-free approach towards an N-heterocyclic carbene (NHC)-coordinated disilene 2 is described. Compound 2, featuring the disilene incorporated in cyclopolysilane framework, was obtained in good yield and characterized using NMR spectroscopy and X-ray crystallography. Density functional theory (DFT) calculations of the reaction mechanism provide a rationale for the observed reactivity and give detailed information on the bonding situation of the base-stabilized disilene. Compound 2 undergoes thermal or light- induced (λ=456 nm) NHC loss, and a dimerization process to give a corresponding dimer with a Si₁₀ skeleton. In order to shed light on the dimerization mechanism, DFT calculations were performed. Moreover, the reactivity of 2 was examined with selected examples

SUBMITTER: Lainer T 

PROVIDER: S-EPMC8889510 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature