Photoactive Fe Catalyst for Light-Triggered Alkyd Paint Curing.

ABSTRACT: Herein, we show that the photoactive complexes [(Cp)Fe(arene)]⁺ (Cp = cyclopentadienyl; arene = C₆H₆, C₆H₅Me) act as latent catalysts that allow for photochemical control over the onset of alkyd paint curing, without the need for antiskinning agents such as the volatile 2-butanone oxime normally used to prevent curing during paint storage. The highly soluble neutral complexes [(Cp)Fe(Ch)] and [(Cp)Fe(Ch')] (Ch = cyclohexadienyl, Ch' = methylcyclohexadienyl) readily convert to the photoactive complexes [(Cp)Fe(arene)]⁺ upon oxidation in alkyd, allowing the latter to be dosed in a wide range of concentrations. Infrared and Raman studies show similar spectral changes of the alkyd paint matrix as have been observed in alkyd curi

SUBMITTER: Bootsma J 

PROVIDER: S-EPMC8889616 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature