Polyamide-MIL-101(Cr) Thin Films Synthesized on Either the Outer or Inner Surfaces of a Polysulfone Hollow Fiber for Water Nanofiltration.

ABSTRACT: High-performance thin film nanocomposite (TFN) hollow fiber (HF) membranes, with MIL-101(Cr) MOF nanoparticles (52 ± 13 nm) embedded, have been synthesized with the polyamide layer formed either on the outer or inner surface of a polysulfone HF (250 and 380 μm ID and OD, respectively). The TFN_out membrane was developed using the conventional interfacial polymerization method, typically applied to obtain TFN flat membranes (MOF particles added to the thin layer by deposition). This membrane gave a water permeance value of 1.0 ± 0.7 L·m^-2·h^-1·bar^-1 and a rejection of 90.9 ± 1.2% of acridine orange (AO, 265 Da). In contrast, the TFN_in membrane was synthesized by microfluidic means and gave a significantly higher water permeance of 2.8 ± 0.2 L·m^-2·

SUBMITTER: Echaide-Gorriz C 

PROVIDER: S-EPMC8892444 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature