Gel Electrolyte Constructing Zn (002) Deposition Crystal Plane Toward Highly Stable Zn Anode.

ABSTRACT: Zinc (Zn) metal anode has been widely evaluated in aqueous Zn batteries. Nevertheless, the dendrite formation issue and consecutive side reactions severely impede the practical applications of Zn metal at high current densities. Herein, it is reported that engineering the gel electrolyte with multifunctional charged groups by incorporating a zwitterionic gel poly(3-(1-vinyl-3-imidazolio) propanesulfonate) (PVIPS) can effectively address the abovementioned issues. The charged groups of sulfonate and imidazole in the gel electrolyte can texture the Zn²⁺ nucleation and deposition plane to (002), which possesses a high activation energy to resist side reactions and induce uniform growth of Zn metal for a dendrite-free structure. In addition, the Zn²⁺ solvation structure c

SUBMITTER: Hao Y 

PROVIDER: S-EPMC8895127 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature