Approaching the Spin-Statistical Limit in Visible-to-Ultraviolet Photon Upconversion.

ABSTRACT: Triplet-triplet annihilation photon upconversion (TTA-UC) is a process in which triplet excitons combine to form emissive singlets and holds great promise in biological applications and for improving the spectral match in solar energy conversion. While high TTA-UC quantum yields have been reported for, for example, red-to-green TTA-UC systems, there are only a few examples of visible-to-ultraviolet (UV) transformations in which the quantum yield reaches 10%. In this study, we investigate the performance of six annihilators when paired with the sensitizer 2,3,5,6-tetra(9H-carbazol-9-yl)benzonitrile (4CzBN), a purely organic compound that exhibits thermally activated delayed fluorescence. We report a record-setting internal TTA-UC quantum yield (Φ_UC,g) of 16.8% (out of a 50

SUBMITTER: Olesund A 

PROVIDER: S-EPMC8895402 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature