Designing polymeric membranes with coordination chemistry for high-precision ion separations.

ABSTRACT: State-of-the-art polymeric membranes are unable to perform the high-precision ion separations needed for technologies essential to a circular economy and clean energy future. Coordinative interactions are a mechanism to increase sorption of a target species into a membrane, but the effects of these interactions on membrane permeability and selectivity are poorly understood. We use a multilayered polymer membrane to assess how ion-membrane binding energies affect membrane permeability of similarly sized cations: Cu²⁺, Ni²⁺, Zn²⁺, Co²⁺, and Mg²⁺. We report that metals with higher binding energy to iminodiacetate groups of the polymer more selectively permeate through the membrane in multisalt solutions than single-salt solutions. In cont

SUBMITTER: DuChanois RM 

PROVIDER: S-EPMC8896795 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature