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Synthesis, crystal structure, Hirshfeld surface and void analysis of bis-(μ₂-4-amino-benzoato-κ² O:O')bis-[bis-(4-amino-benzoato-κ² O,O')di-aquathulium(III)] dihydrate.

ABSTRACT: The asymmetric unit of the title compound, [Tm₂(C₇H₆NO₂)₆(H₂O)₄]·2H₂O, contains three 4-amino-benzoate (4ABA) ligands, two coordinated water mol-ecules, a thulium metal ion, and a water mol-ecule of crystallization. The overall structure of the complex (4ABA-Tm) is in the form of a dimer. In the dinuclear thulium complex, symmetry-relevant TmO₈ coordination polyhedra are formed by the O atoms of two chelating 4-amino-benzoate ligands, the O atoms of two non-chelating 4-amino-benzoate ligands, and two water mol-ecules. The Tm-O bond lengths range from 2.216 (3) to 2.471 (3) Å with the Tm⋯Tm separation in the dinuclear complex being 4.7863 (5) Å. The crystal structure features O-H

SUBMITTER: Ali KS

PROVIDER: S-EPMC8900513 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature

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Dataset Information

Synthesis, crystal structure, Hirshfeld surface and void analysis of bis-(μ₂-4-amino-benzoato-κ² O:O')bis-[bis-(4-amino-benzoato-κ² O,O')di-aquathulium(III)] dihydrate.

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Synthesis, crystal structure, Hirshfeld surface and void analysis of bis-(μ2-4-amino-benzoato-κ2 O:O')bis-[bis-(4-amino-benzoato-κ2 O,O')di-aquathulium(III)] dihydrate.

OmicsDI is part of the ELIXIR infrastructure

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Synthesis, crystal structure, Hirshfeld surface and void analysis of bis-(μ₂-4-amino-benzoato-κ² O:O')bis-[bis-(4-amino-benzoato-κ² O,O')di-aquathulium(III)] dihydrate.