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Crystal structure of tris-(4,7-diphenyl-1,10-phenanthroline-κ2 N,N')cobalt(III) tris-(hexa-fluoro-phosphate) monohydrate.

ABSTRACT: The title compound, [Co(C72H48N6)](PF6)3·H2O, crystallizes with one tripositive complex mol-ecule, three hexa-fluoro-phosphate anions and one solvent mol-ecule of water in the asymmetric unit. The N6 coordination set around the central CoIII atom defines a distorted octa-hedral environment. Four fluorine atoms of one hexa-fluoro-phosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697 (5) and 0.303 (5). In the crystal, inter-molecular π-π stacking inter-actions, C-H⋯π, C-H⋯F and O-H⋯F and inter-actions are present.

SUBMITTER: Mani A 

PROVIDER: S-EPMC8900514 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature

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Crystal structure of tris-(4,7-diphenyl-1,10-phenanthroline-κ<sup>2</sup> <i>N</i>,<i>N</i>')cobalt(III) tris-(hexa-fluoro-phosphate) monohydrate.

Mani Asma A   Belgaied Jamel Eddine JE   Gasser Gilles G   Blacque Olivier O  

Acta crystallographica. Section E, Crystallographic communications 20220210 Pt 3

The title compound, [Co(C<sub>72</sub>H<sub>48</sub>N<sub>6</sub>)](PF<sub>6</sub>)<sub>3</sub>·H<sub>2</sub>O, crystallizes with one tripositive complex mol-ecule, three hexa-fluoro-phosphate anions and one solvent mol-ecule of water in the asymmetric unit. The N<sub>6</sub> coordination set around the central Co<sup>III</sup> atom defines a distorted octa-hedral environment. Four fluorine atoms of one hexa-fluoro-phosphate anion are disordered over two sets of positions with site-occupancy fac  ...[more]

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