Mechanism of the trivalent lanthanides' persistent luminescence in wide bandgap materials.

ABSTRACT: The trivalent lanthanides have been broadly utilized as emitting centers in persistent luminescence (PersL) materials due to their wide emitting spectral range, which thus attract considerable attention over decades. However, the origin of the trivalent lanthanides' PersL is still an open question, hindering the development of excellent PersL phosphors and their broad applications. Here, the PersL of 12 kinds of the trivalent lanthanides with the exception of La³⁺, Lu³⁺, and Pm³⁺ is reported, and a mechanism of the PersL of the trivalent lanthanides in wide bandgap hosts is proposed. According to the mechanism, the excitons in wide bandgap materials transfer their recombination energy to the trivalent lanthanides that bind the excitons, followed by the gene

SUBMITTER: Li L 

PROVIDER: S-EPMC8901650 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature