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MicroED characterization of a robust cationic σ-alkane complex stabilized by the [B(3,5-(SF₅)₂C₆H₃)₄]^- anion, via on-grid solid/gas single-crystal to single-crystal reactivity.

ABSTRACT: Microcrystalline (∼1 μm) [Rh(Cy₂PCH₂CH₂PCy₂)(norbornadiene)][S-BAr^F₄], [S-BAr^F₄] = [B(3,5-(SF₅)₂C₆H₃)₄]^-, reacts with H₂ in a single-crystal to single-crystal transformation to form the σ-alkane complex [Rh(Cy₂PCH₂CH₂PCy₂)(norbornane)][S-BAr^F₄], for which the structure was determined by microcrystal Electron Diffraction (microED), to 0.95 Å resolution, via an on-grid hydrogenation, and a complementary single-crystal X-ray diffraction study on larger, but challenging to isolate, crystals. Comparison with the [BAr^F₄]^- analogu

SUBMITTER: Doyle LR

PROVIDER: S-EPMC8902584 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

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MicroED characterization of a robust cationic σ-alkane complex stabilized by the [B(3,5-(SF₅)₂C₆H₃)₄]^- anion, via on-grid solid/gas single-crystal to single-crystal reactivity.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

MicroED characterization of a robust cationic σ-alkane complex stabilized by the [B(3,5-(SF5)2C6H3)4]- anion, via on-grid solid/gas single-crystal to single-crystal reactivity.

OmicsDI is part of the ELIXIR infrastructure

Tweets

MicroED characterization of a robust cationic σ-alkane complex stabilized by the [B(3,5-(SF₅)₂C₆H₃)₄]^- anion, via on-grid solid/gas single-crystal to single-crystal reactivity.