Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides.

ABSTRACT: Spontaneous migration of atomic hydrogen species from metal particles to the surface of their support, known as hydrogen spillover, has been claimed to play a major role in catalytic processes involving hydrogen. While this phenomenon is well established on reducible oxide supports, its realization on much more commonly used non-reducible oxides is still challenged. Here we present a general strategy to enable effective hydrogen spillover over non-reducible SiO₂ with aid of gaseous organic molecules containing a carbonyl group. By using hierarchically-porous-SiO₂-supported bimetallic Pt-Fe catalysts with Pt nanoparticles exclusively deposited into the micropores, we demonstrate that activated hydrogen species generated on the Pt sites within the micropores can be read

SUBMITTER: Tan M 

PROVIDER: S-EPMC8933562 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature