Direct investigation of the reorientational dynamics of A-site cations in 2D organic-inorganic hybrid perovskite by solid-state NMR.

ABSTRACT: Limited methods are available for investigating the reorientational dynamics of A-site cations in two-dimensional organic-inorganic hybrid perovskites (2D OIHPs), which play a pivotal role in determining their physical properties. Here, we describe an approach to study the dynamics of A-site cations using solid-state NMR and stable isotope labelling. ²H NMR of 2D OIHPs incorporating methyl-d₃-ammonium cations (d₃-MA) reveals the existence of multiple modes of reorientational motions of MA. Rotational-echo double resonance (REDOR) NMR of 2D OIHPs incorporating ¹⁵N- and ¹³C-labeled methylammonium cations (¹³C,¹⁵N-MA) reflects the averaged dipolar coupling between the C and N nuclei undergoing different modes of motions. Our study reveals the interplay between the A-site cation dynamics and the structural rigidity of the organic spacers, so providing a molecular-level insight into the design of 2D OIHPs.

SUBMITTER: Lin CC 

PROVIDER: S-EPMC8938534 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature