Digold(I) Thianthrenyl Complexes. Effect of Diphosphine Ligands on Molecular Structures in the Solid State and in Solution.

ABSTRACT: A series of digold complexes possessing two thianthrenyl ligands, Au₂(Thi)₂(Ph₂P(CH₂) _n PPh₂) (Thi: 1-thianthrenyl; 1: n = 1, 2: n = 2, 3: n = 3, 4: n = 4), were prepared and characterized by crystallographic and spectroscopic measurements. X-ray crystallography of complexes 1 and 3 revealed U-shaped structures with short Au-Au distances [3.2171(3) Å and 3.0735(2) Å]. Complex 2 and three of the four structure-determined molecules of complex 4 showed structures without Au-Au contacts. UV-vis spectroscopic measurements of 1-4 and TD-DFT calculations of the two conformers of 1 revealed that complexes 1 and 3

SUBMITTER: Abe R 

PROVIDER: S-EPMC8945089 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature