Steered polymorphic nanodomains in TiO₂ to boost visible-light photocatalytic oxidation.

ABSTRACT: A breakthrough in enhancing visible-light photocatalysis of wide-bandgap semiconductors such as prototypical titania (TiO₂) via cocatalyst decoration is still challenged by insufficient heterojunctions and inevitable interfacial transport issues. Herein, we report a novel TiO₂-based composite material composed of in situ generated polymorphic nanodomains including carbon nitride (C₃N₄) and (001)/(101)-faceted anatase nanocrystals. The introduction of ultrafine C₃N₄ results in the generation of many oxygen vacancies in the TiO₂ lattice, and simultaneously induces the exposure and growth of anatase TiO₂(001) facets with high surface energy. The photocatalytic performance of C₃N

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC8959444 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature