Application of a conversion electrode based on decomposition derivatives of Ag4[Fe(CN)6] for aqueous electrolyte batteries.
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ABSTRACT: The lack of stable electrode materials for water-based electrolytes due to the intercalation and conversion reaction mechanisms encourage scientists to design new or renovate existing materials with better cyclability, capacity, and cost-effectiveness. Ag4[Fe(CN)6] is a material belonging to the Prussian blue family that can be used, as its other family members, as an electrode material with the intercalation/deintercalation reaction or conversion-type mechanism through Ag oxidation/reduction. However, due to the instability of this material in its dry state, it decomposes to AgCN and a Prussian blue residual complex. A possible reason for Ag4[Fe(CN)6] decomposition is discussed. Nevertheless, it is shown that the decomposition products of Ag
SUBMITTER: Malchik F
PROVIDER: S-EPMC8963386 | biostudies-literature | 2022 Mar
REPOSITORIES: biostudies-literature
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