Lipase-catalyzed acylation of levoglucosan in continuous flow: antibacterial and biosurfactant studies.
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ABSTRACT: Studies involving the transformation of lignocellulosic biomass into high value-added chemical products have been intensively conducted in recent years. Its matrix is mainly composed of cellulose, hemicellulose and lignin, being, therefore, an abundant and renewable source for obtaining several platform molecules, with levoglucosan (LG) standing out. This anhydrous carbohydrate can be acylated to obtain carbohydrate fatty acid esters (CFAEs). Here, these compounds were obtained via enzymatic acylation of LG, commercially obtained (Start BioScience®), with different acyl donors in continuous flow. Through the experimental design using a model reaction, it was possible to optimize the reaction conditions, temperature and residence time, obtaining a maximum conversion at 61 °C and 77 m
SUBMITTER: do Nascimento MA
PROVIDER: S-EPMC8979102 | biostudies-literature | 2022 Jan
REPOSITORIES: biostudies-literature
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