Synthesis, structural and electrical characterization of a new organic inorganic bromide: [(C₃H₇)₄N]₂CoBr₄.

ABSTRACT: A new organic inorganic hybrid [TPA]₂CoBr₄, where TPA = [(C₃H₇)₄N]⁺ (i.e., tetra-propyl-ammonium) compound has been synthesized by slow evaporation method at room temperature. Single crystal X-ray diffraction (SC-XRD), X-ray powder diffraction (XRPD), thermal analyses, vibrational and complex impedance spectroscopy have been used to characterize both structural, thermal, electrical properties. [TPA]₂CoBr₄ crystallizes in the monoclinic system (C2/c space group) with the following cell parameters: a = 33.145 (5) Å, b = 14.234 (3) Å, c = 15.081 (2) Å and β = 110.207 (5)°. In the crystal structure, the organic TPA cations which form layers stacked along the

SUBMITTER: Khalfa M 

PROVIDER: S-EPMC8979218 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature