Synthesis of an Fe(terpy-cage)₂ dumbbell.

ABSTRACT: An azide masked amine is used to obtain a cage of lower symmetry that possess one terpy-group in an exo-position. This group can coordinate to iron(ii), yielding selectively an easy to purify Fe(terpy-cage)₂ dumbbell. The dumbbell can also be obtained in a one pot reaction, which proceeded without isolation of the exo-functionalized cage.

SUBMITTER: Dournel F 

PROVIDER: S-EPMC8979284 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature