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Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones.

ABSTRACT: The preparation of symmetrical (hetero)biaryls via arylazo sulfones has been successfully carried out upon visible light irradiation in the presence of PPh₃AuCl as the catalyst. The present protocol led to the efficient synthesis of a wide range of target compounds in an organic-aqueous solvent under photocatalyst-free conditions.

SUBMITTER: Di Terlizzi L

PROVIDER: S-EPMC8981317 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature

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Visible Light-Driven, Gold(I)-Catalyzed Preparation of Symmetrical (Hetero)biaryls by Homocoupling of Arylazo Sulfones.

Di Terlizzi Lorenzo L Scaringi Simone S Raviola Carlotta C Pedrazzani Riccardo R Bandini Marco M Fagnoni Maurizio M Protti Stefano S

The Journal of organic chemistry 20220322 7

The preparation of symmetrical (hetero)biaryls via arylazo sulfones has been successfully carried out upon visible light irradiation in the presence of PPh<sub>3</sub>AuCl as the catalyst. The present protocol led to the efficient synthesis of a wide range of target compounds in an organic-aqueous solvent under photocatalyst-free conditions. ...[more]

PMID: 35316603

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