Voltammetric and impedimetric determinations of selenium(iv) by an innovative gold-free poly(1-aminoanthraquinone)/multiwall carbon nanotube-modified carbon paste electrode.

ABSTRACT: Selenite (Se⁴⁺), a significant source of water pollution above the permissible limits, is considered a valuable metal by environmentalists. In this study, we described a novel electrochemical sensor that utilized a carbon paste electrode (CPE) that was modified using multiwall carbon nanotubes (MWCNTs) and poly(1-aminoanthraquinone) (p-AAQ) for finding Se⁴⁺ in water samples. Electrochemical quantification of Se⁴⁺ depends on the formation of a selective complex (piaselenol) with p-AAQ. In this work, we prepared a CPE modified by physical embedding of MWCNTs and 1-aminoanthraquione (AAQ), while the polymer film was formed by anodic polymerization of AAQ by applying a constant potential of 0.75 V in 0.1 M HCl for 20 s followed by cyclic voltammetry (CV) from -

SUBMITTER: Ali AG 

PROVIDER: S-EPMC8981389 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature