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The channel structure of trithallium penta-anti-m-on-ate(V), Tl₃Sb₅O₁₄.

ABSTRACT: Single crystals of Tl₃Sb₅O₁₄ were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K₃Sb₅O₁₄, Rb₃Sb₅O₁₄ and Cs₃Sb₅O₁₄ analogues with ortho-rhom-bic Pbam symmetry and cell parameters a = 24.2899 (9) Å, b = 7.1931 (3) Å, c = 7.4182 (3) Å. The Sb atoms form irregular [SbO₆] octa-hedra, which are linked via edges and corners into a triperiodic network. The Tl⁺ ions are located in distinct channels of the network extending along [010] and [001].

SUBMITTER: Sicher P

PROVIDER: S-EPMC8983969 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature

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The channel structure of trithallium penta-anti-m-on-ate(V), Tl3Sb5O14.

Sicher Paul P Stöger Berthold B

Acta crystallographica. Section E, Crystallographic communications 20220317 Pt 4

Single crystals of Tl3Sb5O14 were grown by solid-state reaction in a corundum crucible under air (1273 K, 12 h). The structure was determined by single-crystal X-ray diffraction. It is isotypic to the K3Sb5O14, Rb3Sb5O14 and Cs3Sb5O14 analogues with ortho-rhom-bic Pbam symmetry and cell parameters a = 24.2899 (9) Å, b = 7.1931 (3) Å, c = ...[more]

PMID: 35492267

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