Organic-inorganic hybrid mixed-halide Zn^II and Cd^II tetra-halometallates with the 2-methyl-imidazo[1,5-a]pyridinium cation.

ABSTRACT: Three isomorphous 0-D hybrid salts, namely, 2-methyl-imidazo[1,5-a]pyridinium tri-chlorido-iodido-zincate(II), (C₈H₉N₂)₂[ZnCl_3.19I_0.81] or [L]₂[ZnCl_3.19I_0.81], (I), 2-methyl-imidazo[1,5-a]pyridinium di-bromido-dichlorido-cadmate(II), (C₈H₉N₂)₂[CdBr_2.42Cl_1.58] or [L]₂[CdBr_2.42Cl_1.58], (II), and 2-methyl-imidazo[1,5-a]pyridinium tri-chlorido-iodido-cadmate(II), (C₈H₉N₂)₂[CdCl_3.90I_0.10] or [L]₂[CdCl_3.90I_0.10], (III), are assembled from discrete 2-methyl-imidazo[1,5-a]pyridinium cations, L ⁺, and mixed-halide tetra-halometallate anions. In the three structures, there are two crystallographically non-equivalent cations that were modelled as being rotationally disordered by 180°. In the lattices of the three compounds, a disordered state exists involving partial substitution of Cl by I for sites 2-4 in (I), Br by Cl for all four sites in (II) and Cl by I for site 2 in (III). In the solid state, the organic and inorganic sheets alternate parallel to the bc plane in a pseudo-layered arrangement. In the organic layer, pairs of centrosymmetic-ally related trans-oriented cations form π-bonded chains. The adjacent tetra-halometallate anions in the inorganic layer show no connectivity with the shortest M⋯M separations being greater than 7 Å. A variety of C-H⋯X-M (X = Cl, Br, I) contacts between the organic and inorganic counterparts provide additional structural stabilization. The title structures are isomorphous with the previously reported structures of the chloride analogues, [L]₂[ZnCl₄] and [L]₂[CdCl₄].

SUBMITTER: Vassilyeva OY 

PROVIDER: S-EPMC8983982 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature