Activation of the C[double bond, length as m-dash]P bond in phosphanylphosphaalkenes (C[double bond, length as m-dash]P-P bond system) in the reaction with nucleophilic reagents: MeLi, nBuLi and tBuLi.

ABSTRACT: Three reactions of phosphanylphosphaalkene (1) with nucleophiles were performed to activate the diphosphorus monomer. We observed similar results in the reactions with MeLi and nBuLi, in which the P-P bond is cleavaged and triphosphorus systems [P(Me)₂-CH(biph)-CH(biph)-P-(PtBu₂)]^- (1a'') and [P(nBu)₂-CH(biph)-CH(biph)-P-(PtBu₂)]^- (1b''), respectively, are formed depending on the nucleophilic reagent (biph = biphenyl). In the case of tBuLi, the P-P bond remains intact; on the phosphorus atom, only one -tBu group is substituted, and as a result, [(biph)(H)C-P(tBu)-PtBu₂]^- (1c) is generated as a stable carbanion. We additionally investigated the effe

SUBMITTER: Ziolkowska A 

PROVIDER: S-EPMC8988267 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature