Dataset Information

Wool-Based Carbon Fiber/MoS2 Composite Prepared by Low-Temperature Catalytic Hydrothermal Method and Its Application in the Field of Gas Sensors.

ABSTRACT: Under the background of the Paris Agreement on reducing greenhouse gases, waste wools were converted into wool carbon fiber (WCF) and WCF-MoS2 composites by low-temperature catalytic hydrothermal carbonization. Their structures and gas-sensing performances were studied for the first time. Due to the existence of heterojunctions, the responses of the WCF-MoS2 composite to the five analytes were 3-400 times those of MoS2 and 2-11 times those of WCF. Interestingly, because of the N, P, and S elements contained in wools, the WCF prepared by the hydrothermal method was realized the doping of N, P, and S, which caused the sensing curves of WCF to have different shapes for different analytes. This characteristic was also well demonstrated by the WCF-MoS2 composite, which inspired us to realize the discriminative detection only by a single WCF-MoS2 sensor and image recognition technology. What's more, the WCF-MoS2 composite also showed a high sensitivity, a high selectivity, and a rapid response to NH3. The response time and the recovery time to 3 ppm NH3 were about 16 and 5 s, respectively. The detection of limit of WCF-MoS2 for NH3 was 19.1 ppb. This work provides a new idea for the development of sensors and the resource utilization of wool waste.

SUBMITTER: Xia Y

PROVIDER: S-EPMC9000424 | biostudies-literature | 2022 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Wool-Based Carbon Fiber/MoS2 Composite Prepared by Low-Temperature Catalytic Hydrothermal Method and Its Application in the Field of Gas Sensors.

Xia Yidan Y Wu Zhaofeng Z Qin Zhangjie Z Chen Fengjuan F Lv Changwu C Zhang Min M Shaymurat Talgar T Duan Haiming H

Nanomaterials (Basel, Switzerland) 20220328 7

Under the background of the Paris Agreement on reducing greenhouse gases, waste wools were converted into wool carbon fiber (WCF) and WCF-MoS2 composites by low-temperature catalytic hydrothermal carbonization. Their structures and gas-sensing performances were studied for the first time. Due to the existence of heterojunctions, the responses of the WCF-MoS2 composite to the five analytes were 3-400 times those of MoS2 and 2-11 times those of WCF. Interestingly, ...[more]

PMID: 35407223

Similar Datasets

Project description:Optical fiber (OF) sensors are critical optical devices with excellent sensing capabilities and the capacity to operate in remote and hostile environments. However, integrating functional materials and micro/nanostructures into the optical fiber systems for specific sensing applications has limitations of compatibility, readiness, poor control, robustness, and cost-effectiveness. Herein, we have demonstrated the fabrication and integration of stimuli-responsive optical fiber probe sensors using a novel, low-cost, and facile 3D printing process. Thermal stimulus-response of thermochromic pigment micro-powders was integrated with optical fibers by incorporating them into ultraviolet-sensitive transparent polymer resins and then printed via a single droplet 3D printing process. Hence, the thermally active polymer composite fibers were grown (additively manufactured) on top of the commercial optical fiber tips. Then, the thermal response was studied within the temperature range of (25-35 °C) and (25-31 °C) for unicolor and dual color pigment powders-based fiber-tip sensors, respectively. The unicolor (with color to colorless transition) and dual color (with color to color transition) powders-based sensors exhibited substantial variations in transmission and reflection spectra by reversibly increasing and decreasing temperatures. The sensitivities were calculated from the transmission spectra where average change in transmission spectra was recorded as 3.5% with every 1 °C for blue, 3% for red and 1% for orange-yellow thermochromic powders based optical fiber tip sensors. Our fabricated sensors are cost-effective, reusable, and flexible in terms of materials and process parameters. Thus, the fabrication process can potentially develop transparent and tunable thermochromic sensors for remote sensing with a much simpler manufacturing process compared to conventional and other 3D printing processes for optical fiber sensors. Moreover, this process can integrate micro/nanostructures as patterns on the optical fiber tips to increase sensitivity. The developed sensors may be employed as remote temperature sensors in biomedical and healthcare applications.

Project description:Graphene oxide (GO) oligo-layered laminates were self-assembled on porous ceramic substrates via their simple dip-coating into aqueous GO dispersions. To augment the stability of the developed composite GO/ceramic membranes and control the morphology and stacking quality of the formed laminate, short-((3-glycidoxypropyl)trimethoxy silane-GLYMO, (3-aminopropyl)triethoxy silane-APTES), and long-chain (polydopamine-PDA) molecules were involved and examined as interfacial linkers. A comparative study was performed regarding the linker's capacity to enhance the interfacial adhesion between the ceramic surface and the GO deposit and affect the orientation and assemblage characteristics of the adjacent GO nanosheets that composed the formed oligo-layered laminates. Subsequently, by post-filtrating a GO/H2O suspension through the oligo-layered laminate membranes, the respective multi-layered ones have been developed, whereas ethylenediamine (EDA) was used in the suspension as an efficient molecular linker that strongly bonds and interlocks the GO nanosheets. The definition of the best linker and approach was conducted on macroporous α-alumina disks, due to the use of inexpensive raw materials and the ability to fabricate them in the lab with high reproducibility. To validate the concept at a larger scale, while investigating the effect of the porous substrate as regards its micrometer-scale roughness and surface chemistry, specific chemical modifications that yielded membranes with the best gas permeability/selectivity performance were replicated on a commercial single-channel monolith with a ZrO2 microfiltration layer. XRD, Raman, ATR, FESEM, and XPS analyses were conducted to study the structural, physicochemical, surface, and morphological properties of the GO/ceramic composite membranes, whereas permeance results of several gases at various temperatures and trans-membrane pressures were interpreted to shed light on the pore structural features. Concerning the short-chain linkers, the obtained results ascertain that GLYMO causes denser and more uniform assembly of GO nanosheets within the oligo-layered laminate. PDA had the same beneficial effect, as it is a macromolecule. Overall, this study shows that the development of gas-separating membranes, by just dipping the linker-modified substrate into the GO suspension, is not straightforward. The application of post-filtration contributed significantly to this target and the quality of the superficially deposited, thick GO laminate depended on this of the chemically attached oligo-layered one.

Dataset Information

Wool-Based Carbon Fiber/MoS2 Composite Prepared by Low-Temperature Catalytic Hydrothermal Method and Its Application in the Field of Gas Sensors.

Publications

Wool-Based Carbon Fiber/MoS<sub>2</sub> Composite Prepared by Low-Temperature Catalytic Hydrothermal Method and Its Application in the Field of Gas Sensors.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets